The form of the collision function can be found [11, 12, 14] by assuming that the gas has a low density so only binary collisions need be considered. It is also assumed that the molecules are completely uncorrelated before the collision, this assumption is called `molecular chaos'. With these assumptions the collision function is given by [11, 12, 14]
where and are the velocities of the two particles before a collision, and are their velocities after the collision, , , , , g is the magnitude of the particles relative velocity before the collision, is the solid angle the particles are scattered into,
and is the differential cross section in the centre of mass reference frame,
where b and are the impact parameter and the scattering angle respectively in the centre of mass reference frame, as defined in figure 2-1, is the azimuthal angle.
Figure 2-1: Two particles (of equal mass) before and
after a collision in the centre of mass reference frame. The impact parameter
b and the angle are shown.