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The Collision Function

The form of the collision function tex2html_wrap_inline12893 can be found [11, 12, 14] by assuming that the gas has a low density so only binary collisions need be considered. It is also assumed that the molecules are completely uncorrelated before the collision, this assumption is called `molecular chaos'. With these assumptions the collision function is given by [11, 12, 14]

  equation432

where tex2html_wrap_inline13137 and tex2html_wrap_inline13139 are the velocities of the two particles before a collision, tex2html_wrap_inline12921 and tex2html_wrap_inline13143 are their velocities after the collision, tex2html_wrap_inline13145 , tex2html_wrap_inline13147 , tex2html_wrap_inline13149 , tex2html_wrap_inline13151 , g is the magnitude of the particles relative velocity before the collision, tex2html_wrap_inline13155 is the solid angle the particles are scattered into,

equation451

and tex2html_wrap_inline13157 is the differential cross section in the centre of mass reference frame,

equation456

where b and tex2html_wrap_inline12063 are the impact parameter and the scattering angle respectively in the centre of mass reference frame, as defined in figure 2-1, tex2html_wrap_inline13163 is the azimuthal angle.

   figure463
Figure 2-1: Two particles (of equal mass) before and after a collision in the centre of mass reference frame. The impact parameter b and the angle tex2html_wrap_inline12063 are shown.



James Buick
Tue Mar 17 17:29:36 GMT 1998